An efficient indium-mediated 2-bromoallylation of aldehydes at low temperature in aqueous DMF
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- Title
- An efficient indium-mediated 2-bromoallylation of aldehydes at low temperature in aqueous DMF
- Author(s)
- Y M Kim; Sangku Lee; S H Kim; J N Kim
- Bibliographic Citation
- Tetrahedron Letters, vol. 52, no. 25, pp. 3240-3242
- Publication Year
- 2011
- Abstract
- An efficient synthesis of 2-bromohomoallylic alcohols was carried out via an indium-mediated Barbier-type 2-bromoallylation of aldehydes in moderate yields. The reaction was performed at low temperature (-20 °C) in aqueous DMF in order to minimize decomposition of 2-bromoallylindium reagent to allene.
- ISSN
- 0040-4039
- Publisher
- Elsevier
- Full Text Link
- http://dx.doi.org/10.1016/j.tetlet.2011.04.053
- Type
- Article
- Appears in Collections:
- Ochang Branch Institute > Chemical Biology Research Center > 1. Journal Articles
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