An efficient indium-mediated 2-bromoallylation of aldehydes at low temperature in aqueous DMF

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Title
An efficient indium-mediated 2-bromoallylation of aldehydes at low temperature in aqueous DMF
Author(s)
Y M Kim; Sangku Lee; S H Kim; J N Kim
Bibliographic Citation
Tetrahedron Letters, vol. 52, no. 25, pp. 3240-3242
Publication Year
2011
Abstract
An efficient synthesis of 2-bromohomoallylic alcohols was carried out via an indium-mediated Barbier-type 2-bromoallylation of aldehydes in moderate yields. The reaction was performed at low temperature (-20 °C) in aqueous DMF in order to minimize decomposition of 2-bromoallylindium reagent to allene.
Keyword
2-BromoallylationAlleneBarbier reactionIndium
ISSN
0040-4039
Publisher
Elsevier
DOI
http://dx.doi.org/10.1016/j.tetlet.2011.04.053
Type
Article
Appears in Collections:
Ochang Branch Institute > Chemical Biology Research Center > 1. Journal Articles
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