Enantioselective syntheses of decursinol angelate and decursin
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Title
Enantioselective syntheses of decursinol angelate and decursin
Author(s)
Jong Doo Lim; Ik Hwan Kim; Hyeon Ho Kim; Kyung Seop Ahn; Hog Yu Han
Bibliographic Citation
Tetrahedron Letters, vol. 42, no. 24, pp. 4001-4003
Publication Year
2001
Abstract
The practical enantioselective syntheses of decursinol angelate and decursin were achieved in eight steps from resorcinol. The stereochemistry was addressed using the catalytic asymmetric epoxidation of 7-acetoxy-2,2-dimethylchromene by chiral (salen)Mn complexes as the key step.