Total synthesis and absolute stereochemistry of (9R,10S)-epoxyheptadecan-4,6-diyn-3-one, a diacylglycerol acyltransferase inhibitor from Panax ginseng

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Title
Total synthesis and absolute stereochemistry of (9R,10S)-epoxyheptadecan-4,6-diyn-3-one, a diacylglycerol acyltransferase inhibitor from Panax ginseng
Author(s)
Jung-Hoon Oh; Hyun Sun LeeMun Chual Rho; Young Kook Kim; Hyeong Kyu Lee; Woo Song Lee; J N Kim; Sangku Lee; S H Jung
Bibliographic Citation
Tetrahedron Letters, vol. 45, no. 38, pp. 7077-7079
Publication Year
2004
Abstract
Asymmetric synthesis of four possible stereoisomers of (9,10)- epoxyheptadecan-4,6-diyn-3-one was accomplished, and the absolute configuration of the naturally occurring (9R,10S)-epoxyheptadecan-4,6-diyn-3-one (1) was elucidated.
Keyword
absolute configurationasymmetric synthesisepoxidationstereochemistrytotal synthesis
ISSN
0040-4039
Publisher
Elsevier
DOI
http://dx.doi.org/10.1016/j.tetlet.2004.07.153
Type
Article
Appears in Collections:
Ochang Branch Institute > Natural Medicine Research Center > 1. Journal Articles
Jeonbuk Branch Institute > Immunoregulatory materials Research Center > 1. Journal Articles
Jeonbuk Branch Institute > Functional Biomaterial Research Center > 1. Journal Articles
Ochang Branch Institute > Anticancer Agent Research Center > 1. Journal Articles
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