Regioselective synthesis of poly-substituted naphthalenes via a Pd-catalyzed cyclization of modified Baylis?Hillman adducts: selective 6-endo Heck reaction and an aerobic oxidation cascade = 다중치환된 나프탈렌의 선택적 합성

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Title
Regioselective synthesis of poly-substituted naphthalenes via a Pd-catalyzed cyclization of modified Baylis?Hillman adducts: selective 6-endo Heck reaction and an aerobic oxidation cascade = 다중치환된 나프탈렌의 선택적 합성
Author(s)
S H Kim; Sangku Lee; H S Lee; J N Kim
Bibliographic Citation
Tetrahedron Letters, vol. 51, no. 48, pp. 6305-6309
Publication Year
2010
Abstract
Poly-substituted naphthalenes were synthesized via a Pd-catalyzed cyclization of modified Baylis-Hillman adducts having an o-bromophenyl acetonitrile moiety at the secondary position, in reasonable yields. The reaction involved a sequential 6-endo Heck reaction and an aerobic oxidation process.
Keyword
6-endo Heck reactionBaylis-Hillman adductsNaphthalenesPalladium
ISSN
0040-4039
Publisher
Elsevier
DOI
http://dx.doi.org/10.1016/j.tetlet.2010.09.127
Type
Article
Appears in Collections:
Ochang Branch Institute > Anticancer Agent Research Center > 1. Journal Articles
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